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Mild and Highly Efficient Protocol for the Synthesis of Benzimidazoles Using Samarium Triflate [Sm(OTf)3]
Authors:A Venkat Narsaiah  A Ramesh Reddy  J S Yadav
Institution:1. Organic Chemistry Division, Indian Institute of Chemical Technology , Hyderabad, India vnakkirala2001@yahoo.com;3. Organic Chemistry Division, Indian Institute of Chemical Technology , Hyderabad, India
Abstract:One-pot synthesis of benzimidazole compounds from ortho-phenylenediamine and a variety of aldehydes was developed under mild reaction conditions. All the reactions were carried out in the presence of samarium triflate (10 mol%) in acetonitrile at room temperature.
Keywords:Aldehydes  benzimidazoles  ortho-phenylenediamine  samarium triflate
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