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Efficient and Recyclable Reaction System for the Homocoupling of Terminal Acetylenes
Authors:Xiaoling Lu  Chengcai Luo  Yanguang Wang
Affiliation:Department of Chemistry , Zhejiang University , Hangzhou, China
Abstract:Diynes were synthesized in high yields by homocoupling of terminal arylacetylenes and terminal alkylacetylenes in Cu(OAc)2‐PEG (polyethyleneglycol) with NaOAc as a base. Cu(OAc)2‐PEG was readily recycled via solvent precipitation with efficient recyclability.
Keywords:Coupling of terminal acetylene  cupric salt  diyne  PEGs
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