Asymmetric Synthesis of Heptacosane-6,8-Diols Induced by Chiral Sulfoxides |
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| Authors: | Shigeyasu Motohashi Ken Yasukawa Michio Takido Toshihiro Akihisa Torn Takagi Ryota Nishioka |
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| Affiliation: | 1. College of Pharmacy, Nihon University , 7-7-1, Narashinodai, Funabashi-shi, Chiba, 274, Japan;2. College of Science and Technology, Nihon University , 1--8, Kandasurugadai, Chiyoda-ku, Tokyo, 101, Japan;3. Nagoya Bunri College , 2--1, Sasazukamachi, Nishi-ku, Nagoya-shi, Aichi, 451;4. Sumika Chemical Analysis Service , 3-1-135, Kasugadenaka, Konohana-ku, Osaka, 554, Japan |
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| Abstract: | The asymmetric synthesis of (6S,8R)-, (6S,8S)-, (6R,8S)- and (6R,8R)-heptacosane-6,8-diols from (2S)-, (2R)-1-[(R)-p-tolylsulfinyl]-2-heptanols and 1-icosanal is described. |
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| Keywords: | Carboxylic acids N-hydroxysuccinimide N-hydroxysuccinimide esters triphosgene |
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