Acetic Anhydride/Et3N/DMAP: An Effective Acetylating System for Hemiacetals |
| |
| Authors: | Fabrizio Roncaglia Andrew F. Parsons Franco Bellesia Franco Ghelfi |
| |
| Affiliation: | 1. Department of Chemistry , University of Modena and Reggio Emilia , Modena , Italy fabrizio.roncaglia@unimore.it;3. Department of Chemistry , University of York , Heslington , York , UK;4. Department of Chemistry , University of Modena and Reggio Emilia , Modena , Italy |
| |
| Abstract: | The selective and efficient acetylation of the hemiacetal hydroxyl in the equilibrium mixture between RCl2C(OAll)OH and AllOH/RCl2CHO was achieved using the acylating system Ac2O/Et3N/dimethylaminopyridine (DMAP).  Additional information ACKNOWLEDGMENT We thank the Ministero della Istruzione, dell'Università e della Ricerca (MIUR), for financial assistance. |
| |
| Keywords: | Acetylation DMAP haloaldehyde hemiacetal Ueno–Stork |
|
|
