Highly selective synthesis of novel (E)-styrylsilatranes via ruthenium-catalyzed trans-silylation |
| |
| Authors: | Bogna Sztorch Dawid Frąckowiak |
| |
| Institution: | 1. Faculty of Chemistry, Adam Mickiewicz University in Poznań, Poznań, Poland;2. Centre for Advanced Technologies, Adam Mickiewicz University in Poznań, Poznań, Poland |
| |
| Abstract: | Protocols for the synthesis of cage-substituted 1-vinylsilatranes have been developed and updated. The 1-vinylsilatranes with organic substituents attached to silatrane cage were functionalized in ruthenium-catalyzed trans-silylation with olefins, leading to novel styrylsilatranes in high yields. |
| |
| Keywords: | Homogeneous catalysis organosilicon chemistry ruthenium hydride complex silatranes silylative coupling |
|
|
