Highly selective synthesis of novel (E)-styrylsilatranes via ruthenium-catalyzed trans-silylation |
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Authors: | Bogna Sztorch Dawid Fr?ckowiak |
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Institution: | 1. Faculty of Chemistry, Adam Mickiewicz University in Poznań, Poznań, Poland;2. Centre for Advanced Technologies, Adam Mickiewicz University in Poznań, Poznań, Poland |
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Abstract: | Protocols for the synthesis of cage-substituted 1-vinylsilatranes have been developed and updated. The 1-vinylsilatranes with organic substituents attached to silatrane cage were functionalized in ruthenium-catalyzed trans-silylation with olefins, leading to novel styrylsilatranes in high yields. |
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Keywords: | Homogeneous catalysis organosilicon chemistry ruthenium hydride complex silatranes silylative coupling |
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