Iodine Monochloride (ICl) as a Highly Efficient,Green Oxidant for the Oxidation of Alcohols to Corresponding Carbonyl Compounds |
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| Authors: | Peng Wei Zhigang Gao Wenqing Cai Weiren Xu Lida Tang |
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| Affiliation: | 1. School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, China;2. Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China;3. Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China |
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| Abstract: | Iodine monochloride (ICl) was discovered to be a highly efficient, green oxidant, which can oxidize aldose hemiacetals, diarylmethanols, arylalkylmethanols, anddialkylmethanols to the corresponding aldose lactones, diarylmethanones, arylalkylmethanones, and dialkylmethanones, respectively, in high yields. ICl as a green, metal-free oxidant is characterized by mild reaction condition, short reaction time, good yield, and broad scope. |
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| Keywords: | Aldose hemiacetal green oxidant iodine monochloride lactonization synthesis |
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