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Efficient Procedure for Beckmann Rearrangement of Ketoximes Catalyzed by Sulfamic Acid/Zinc Chloride
Authors:Ji-Tai Li  Xian-Tao Meng  Ying Yin
Affiliation:1. College of Chemistry and Environmental Science, Hebei University, Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Medical Chemistry and Molecular Diagnosis, Ministry of Education , Baoding, China lijitai@hbu.cn;3. College of Chemistry and Environmental Science, Hebei University, Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Medical Chemistry and Molecular Diagnosis, Ministry of Education , Baoding, China
Abstract:The Beckmann rearrangement of a variety of ketoximes to corresponding amides catalyzed by sulfamic acid and zinc chloride was carried out in good yields at refluxing temperature in acetonitrile.
Keywords:Amides  Beckmann rearrangement  cocatalyst  ketoxime  synthesis
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