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Cycloaddition of Porphyrins to Isatin: Synthesis of Novel Spiro Porphyrin Derivatives
Authors:Xin‐Gang Liu  Chuang‐Jiang Tan  Hong‐Liang Chen
Institution:Department of Fine Chemicals, School of Chemical Engineering , Tianjin University , Tianjin, China
Abstract:Isatin undergoes regioselective 1,3‐dipolar cycloaddition reactions with porphyrin azomethine ylides derived from Ni(II) β‐formyl‐meso‐tetraphenylporphyrins in the presence of N‐methylglycine to afford novel spiro porphyrin derivatives.
Keywords:1  3‐Dipolar cycloaddition  o‐quinone  porphyrin  spiro porphyrins
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