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Condensation and Dehydration Reactions of L-Sorbose in Ecofriendly Melt Systems
Authors:Carolin Ruß  Alireza Haji Begli
Institution:1. Institute of Organic Chemistry , University of Regensburg , Regensburg , Germany;2. SüDZUCKER AG Mannheim/Ochsenfurt, Central Department Research , Entwicklung, Services (CRDS) , Obrigheim , Germany
Abstract:L-Sorbose 1 was converted to 5-hydroxymethylfurfural 8 in choline chloride melts in moderate yields. A simplified synthesis of sorbosylurea tetraacetate 4 in two steps using urea melts was performed, achieving good yields.

Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file.
Keywords:5-Hydroxymethylfurfural  low melting mixtures  L-sorbose" target="_blank">L-sorbose  sorbosylurea
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