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Chemoselective Addition of Hydrazine to δ‐Keto Esters and Dimethylformamide‐Mediated Deesterification
Authors:Sivaperuman Saravanan  Vellaisamy Sridharan  
Affiliation:Department of Organic Chemistry , Madurai Kamaraj University , Madurai, India
Abstract:The chemoselective reaction of hydrazine on the ketone rather than the ester in a gem diester system with a γ‐keto group by hydrazinium sulfate and a tandem deesterification of one of the esters in this system by N,N‐dimethylformamide are reported.
Keywords:Azines  deesterification  hydrazones  X‐ray structure
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