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Oxidation of Benzyl Halides to Aldehydes and Ketones with Potassium Nitrate Catalyzed by Phase-Transfer Catalyst in Aqueous Media
Authors:Qifa Liu  Feng Sun  Jiang Li  Yuebing Zhao
Affiliation:1. Chemical Engineering College , Nanjing University of Science and Technology , Nanjing, China;2. Nanjing Cosmos Chemical Co. , Nanjing, China
Abstract:The catalytic oxidation of benzyl halides to aldehydes and ketones in aqueous media was studied under relatively mild reaction conditions by using phase-transfer catalyst combined with potassium nitrate and 10% aqueous potassium hydroxide solution. As a result, a simple high-yield procedure has been developed.
Keywords:Benzyl halide  oxidation  phase-transfer catalyst  potassium nitrate
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