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Synthesis and Characterization of Six New Carbazolyl Porphyrins
Authors:Dong-Cai Guo  Ping-Liang Li  Xin Wang  Li-Ying Wang  Pan-Liang Wu
Institution:1. School of Chemistry and Chemical Engineering, Hunan University , Changsha, China dcguo2001@163.com;3. School of Chemistry and Chemical Engineering, Hunan University , Changsha, China
Abstract:Novel 4-(N-carbazole methyl) benzoic acid and N-carbazolacetic acid are synthesized, then six new carbazolyl porphyrins are synthesized by bonding these acids to hydroxy porphyrin or amido porphyrin via acyl chloride or N,N′-dicyclohexylcarbodiimide (DCC)–dimethylaminopyndine methods. The formations of these title compounds, as well as their intermediates are characterized by 1H NMR, mass spectrometry, Fourier transform–infrared, and elemental analysis.
Keywords:Carbazole  porphyrin  synthesis
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