Facile and Convenient Synthesis of Functionalized Aryl-Containing Isoindigo Derivatives via Substituted Indolin-2-one Carbene Dimerization |
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Authors: | Andrei V. Bogdanov Vladimir F. Mironov Lenar I. Musin Rashid Z. Musin Dmitry B. Krivolapov Igor A. Litvinov |
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Affiliation: | 1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences , Kazan , Russia bogdanov@iopc.ru;3. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences , Kazan , Russia |
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Abstract: | The reaction of substituted benzyl-, aroylmethyl-, or 1-phenetylisatins with hexaethyltriaminophosphine has been shown to lead to the formation of a library of 3,3′-biindolinylidene-2,2′-diones with functionalized benzyl-, aroylmethyl-, and 1-phenetyl fragments at the nitrogen atom. |
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Keywords: | Carbenes deoxygenation reaction isatin isoindigo phosphorus |
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