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Facile and Convenient Synthesis of Functionalized Aryl-Containing Isoindigo Derivatives via Substituted Indolin-2-one Carbene Dimerization
Authors:Andrei V. Bogdanov  Vladimir F. Mironov  Lenar I. Musin  Rashid Z. Musin  Dmitry B. Krivolapov  Igor A. Litvinov
Affiliation:1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences , Kazan , Russia bogdanov@iopc.ru;3. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences , Kazan , Russia
Abstract:The reaction of substituted benzyl-, aroylmethyl-, or 1-phenetylisatins with hexaethyltriaminophosphine has been shown to lead to the formation of a library of 3,3′-biindolinylidene-2,2′-diones with functionalized benzyl-, aroylmethyl-, and 1-phenetyl fragments at the nitrogen atom.
Keywords:Carbenes  deoxygenation reaction  isatin  isoindigo  phosphorus
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