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Ionic Liquid Oxidant for Efficient and Selective Oxidation of Benzylic Alcohols
Authors:Rahman Hosseinzadeh  Maryam Mohadjerani  Mahmood Tajbakhsh  Mahboobe Nouzarian
Institution:1. Faculty of Chemistry, Department of Organic Chemistry , Mazandaran University , Babolsar , Iran r.hosseinzadeh@umz.ac.ir;3. Faculty of Science, Department of Biology , Mazandaran University , Babolsar , Iran;4. Faculty of Chemistry, Department of Organic Chemistry , Mazandaran University , Babolsar , Iran
Abstract:Hexamethylenebis (N-methylimidazolium) dichlorochromate was easily prepared by addition of N-methylimidazole to 1,6-dibromohexane to form the corresponding dibromide salt and subsequent treatment with CrO3 in 6 N HCl solution. It is a low-melting orange salt that selectively oxidized benzylic alcohols.

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ACKNOWLEDGMENT

Financial support from the research council of the University of Mazandaran is gratefully acknowledged.
Keywords:Benzylic alcohols  hexamethylenebis (N-methylimidazolium) dichlorochromate  ionic liquid  oxidation
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