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Nucleophilic Reaction of Heterocyclic Enamines with Nitrile imine 1,3-Dipoles
Authors:Wei-Shi Miao  Feng Xiong  Mei-Xiang Wang  Zhi-Tang Huang
Institution:Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences , Beijing, 100080, China
Abstract:Instead of 1,3-dipolar cycloaddition, the nucleophilic addition reaction proceeded smoothly between heterocyclic enamines 1 or 2 and nitrile imine 1,3-dipoles 3 under mild conditions to yield C-hydrazidoyl-substituted heterocyclic enamines 4--6 as the sole product.
Keywords:
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