Nano-TiO2: An Efficient and Reusable Heterogeneous Catalyst for Ring Opening of Epoxides Under Solvent-Free Conditions |
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Authors: | Xi'an Chen Huayue Wu Shun Wang |
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Affiliation: | 1. Nanomaterials and Chemistry Key Laboratory , Wenzhou University , Wenzhou , China xianchen@wzu.edu.cn;3. Nanomaterials and Chemistry Key Laboratory , Wenzhou University , Wenzhou , China |
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Abstract: | Nano-TiO2 is an effective heterogeneous catalyst for the ring opening of epoxides with aromatic amines to afford β-amino alcohols in good to excellent yields at room temperature under solvent-free conditions. It was found that the catalyst is recyclable, and the activity of the catalyst was not weakened markedly even after several reaction cycles. In addition, the catalytic activity of TiO2 strongly depends on particle size or surface area. |
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Keywords: | roman" >β-Amino alcohol epoxide heterogeneous catalyst nano-TiO2 solvent-free |
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