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PdO-Catalyzed Synthesis of Tricyclic Compounds Using Biginelli-Like Reaction
Authors:Xiaobi Jing  Zhen Li  Xin Pan  Qing Wang  Chaoguo Yan  Hongxiang Zhu
Institution:1. Department of Chemistry , Yangzhou University , Yangzhou, Jiangsu, China Jingxiaobi@yahoo.com.cn;3. Department of Chemistry , Yangzhou University , Yangzhou, Jiangsu, China;4. School of Light Industrial and Food Engineering, Guangxi University , Nanning Guangxi, China
Abstract:An efficient method has been successfully developed for the synthesis of oxygen-bridged pyrimidine tricyclic derivatives from salicylaldehyde, ethyl acetoacete, and urea catalyzed by PdO in very good yield. A series of different oxygen-bridged pyrimidine tricyclic derivatives has been synthesized, in which two compounds’ x-ray crystal structure were obtained.
Keywords:Biginelli reaction  oxygen-bridged pyrimidine tricyclic derivatives  PdO
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