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Novel Metal Oxide of CuO-ZnO Nanocatalyst Efficiently Catalyzed the Synthesis of 2-Amino-4H-chromenes in Water
Authors:Jalal Albadi  Amir Alihoseinzadeh  Azam Mansournezhad  Leila Kaveiani
Institution:1. Behbahan Khatam Alanbia University of Technology, Behbahan, IranChemalbadi@gmail.com Albadi@bkatu.ac.ir;3. School of Chemical Engineering, University of Tehran, Tehran, Iran;4. Department of Chemistry, Islamic Azad University, Gachsaran Branch, Gachsaran, Iran
Abstract:Novel metal oxide of CuO-ZnO nanocatalyst was prepared by a coprecipitation method and characterized by x-ray diffusion, Brunauer–Emmett–Teller surface area, scanning electron microscopy, transmission electron microscopy, and energy dispersive spectroscopy (EDS) analysis. The catalyst is efficient for the synthesis of 2-amino-4H-chromenes by one-pot condensation of aromatic aldehydes, hydroxynaphthalene derivatives, and malononitrile in water at reflux conditions. Moreover, CuO-ZnO nanocatalyst can be recycled up six times without any significant loss of its catalytic activity.
Keywords:Aldehyde  2-amino-4H-chromenes  CuO-ZnO nanocatalyst  hydroxynaphthalene  malononitrile
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