A One Pot Synthesis of 5-Phenyl-1,3-Dioxane-4,6-Dione Derivatives |
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| Authors: | K Saidi H R Shaterian H Sheibani |
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| Institution: | Department of Chemistry , Shahid Bahonar University of Kerman , Kerman, 76175, Iran |
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| Abstract: | A general procedure for synthesis of 5-phenyl-1,3-dioxane-4,6-dione derivatives is described. The synthesis involves the cycloaddition of (α-chlorocarbonyl)phenyl ketene with carbonyl compounds to generate the corresponding substituted 2-oxetanone's which is readily transformed to the final products in one step. The 1,3-dioxane-4,6-dione is a rigid cyclic structure, and can undergo easy hydrolysis. |
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| Keywords: | Friedel–Crafts reaction Diaryl naphthyl methanes Molecular rearrangement Lewis acid co‐catalyst Alkylation |
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