Studies of Birch Reductive Alkylation of Substituted α-Tetralones |
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| Authors: | Guillermo R Labadie Raquel M Cravero Manuel Gonzalez-Sierra |
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| Institution: | IQUIOS-(Instituto de Quimica Orgánica de Síntesis), Departamento de Química Orgánica, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario , Suipacha, 531--2000, Rosario-Santa Fe, ARGENTINA Fax: E-mail: iquiosra@citynet.net.ar |
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| Abstract: | A series of α-tetralones, with different degree of substitution, was submitted to the Birch reduction-alkylation procedure using various alkylating agents, to produce angularly substituted 1,4-unsaturated decalones. The stereoselectivity behavior of such dienones upon reduction is also described. |
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| Keywords: | Synthesis Diels–Alder reaction Labdane Drimane Analogues o‐Quinol functionality |
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