| (硫杂)杯[4]芳烃缩氨基(硫)脲(桥联)衍生物的合成 |
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| 引用本文： | 唐富胜,杨发福,黄智胜,洪碧琼,郭红玉.(硫杂)杯[4]芳烃缩氨基(硫)脲(桥联)衍生物的合成[J].有机化学,2009,29(8):1278-1281. |
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| 作者姓名： | 唐富胜 杨发福 黄智胜 洪碧琼 郭红玉 |
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| 作者单位： | 福建师范大学化学与材料学院,福州,350007 |
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| 基金项目： | 国家自然科学基金，福建省自然科学基金，福建省高校新世纪优秀人才支持计划资助项目 |
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| 摘 要： | 对叔丁基(硫杂)杯4]芳烃-1,3-二醛基衍生物4a和4b与苯基氨基硫脲进行“1＋2”缩合反应, 合成了杯4]芳烃缩氨基硫脲衍生物5a和5b, 产率为84%和85%. 化合物4a和4b与1,6-己基双氨基脲发生“1＋1”缩合反应, 合成了杯4]芳烃双缩氨基脲桥联衍生物6a和6b, 产率为83%和80%. 新化合物的结构与构象经元素分析、质谱、核磁共振谱等表征证实.
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| 关 键 词： | (硫杂)杯[4]芳烃 缩氨基脲 合成 桥联
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| 收稿时间： | 2008-11-8 |
| 修稿时间： | 2008-12-22 |
Syntheses of (Thia)calix[4]arene (Thio)semicarbazone(-bridged) Derivatives |
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| Tang Fusheng,Yang Fafu,Huang Zhisheng,Hong Biqiong,Guo Hongyu.Syntheses of (Thia)calix[4]arene (Thio)semicarbazone(-bridged) Derivatives[J].Chinese Journal of Organic Chemistry,2009,29(8):1278-1281. |
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| Authors: | Tang Fusheng Yang Fafu Huang Zhisheng Hong Biqiong Guo Hongyu |
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| Institution: | (College of Chemistry and Materials, Fujian Normal University, Fuzhou 350007) |
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| Abstract: | (Thia)calix4]arene thiosemicarbazone derivatives 5a and 5b were synthesized by “1＋2” condensation of 1,3-bis2-(p-formylphenyloxy)ethyloxy]-p-tert-butylcalix4]arene 4a and 4b with 1-phenyl- thiosemicarbazide in yields of 84% and 85%, respectively. (Thia)calix4]arene semicarbazone-bridged de-rivatives 6a and 6b were prepared by reacting compounds 4a and 4b with 1,6-hexylenebis(1-semicarbazide) in “1＋1” condensation in yields of 83% and 80%, respectively. The structures and conformations of the new compounds were characterized by elemental analyses, ESI-MS, 1H NMR, etc. |
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| Keywords: | (thia)calix[4]arene semicarbazone synthesis bridgi |
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