Mechanism of crystallization of fast fired mullite-based glass–ceramic glazes for floor-tiles |
| |
Affiliation: | Department of Inorganic Chemistry, University of Valencia, Calle Doctor Moliner 50, 46100 Burjasot, Valencia, Spain |
| |
Abstract: | The mechanism of crystallization from a B2O3-containing glass, with composition based in the CaO–MgO–Al2O3–SiO2 system, to a glass–ceramic glaze was studied by different techniques. Glass powder pellets were fast heated, simulating current industrial tile processing methods, at several temperatures from 700 to 1200 °C with a 5 min hold. Microstructural study by field emission scanning electron microscopy revealed that a phase separation phenomenon occurred in the glass, which promoted the onset of mullite crystallization at 900 °C. The amount of mullite in the glass heated between 1100 and 1200 °C was around 20 wt%, as determined by Rietveld refinement. The microstructure of the glass–ceramic glaze heated at 1160 °C consisted of interlocked, well-shaped, acicular mullite crystals longer than 4 μm, immersed in a residual glassy phase. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|