Syntheses and structural characterization of novel heteroannular cyclopalladated ferrocenylimine |
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| Institution: | 1. Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK;2. Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, UK;1. Institut des Sciences Chimiques de Rennes, CORINT, UMR CNRS 6226, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France;2. Research School of Chemistry, Australian National University, Canberra, ACT 2601, Australia;3. Institut des Sciences Chimiques de Rennes, Centre de Diffractométrie X, UMR CNRS 6226, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France;1. Zhengzhou Tobacco Research Institute, CNTC, Zhengzhou 450001, PR China;2. The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, PR China |
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| Abstract: | A new heteroannular cyclopalladated ferrocene derivative PdCl{C5H4FeC5H4CH2N CH–C4H3S}(PPh3)] (6) was synthesized and characterized by IR, 1H NMR, 13C NMR, high resolution mass spectroscopy, and its molecular structure was further confirmed by X-ray crystal structure determination. According to the crystal structure, the palladium atom is bound to the unsubstituted Cp ring, showing the four-coordinate structure typical of palladium complexes. A preliminary application of these novel cyclopalladated complexes in Mizoroki–Heck reaction is also to be demonstrated in this paper. |
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