The crosslinking reaction of acrylic PSA using chelate metal acetylacetonates |
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| Institution: | 1. Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan;2. Industrial Technology Center of Okayama Prefecture, 5301 Haga, Kita-ku, Okayama 701-1296, Japan;3. Nanomaterials Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan;1. Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 119260, Singapore;2. Suzhou Faith & Hope Membrane Technology Co. Ltd., Suzhou Industrial Park, Jiangsu Province 215123, PR China;1. Hasselt University, Institute for Materials Research, Applied and Analytical Chemistry, Agoralaan Gebouw D, B-3590, Diepenbeek, Belgium;2. Technical University Darmstadt, Ernst-Berl-Institute for Technical and Macromolecular Chemistry, Macromolecular Chemistry and Paper Chemistry, Darmstadt, Germany;3. University of Freiburg, Institute for Microsystems Technology (IMTEK), Laboratory for Chemistry and Physics of Interfaces, Freiburg, Germany;1. Laboratory for Atomistic and Molecular Mechanics (LAMM), Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, 1-290, Cambridge, MA 02139, USA;2. Henkel AG & Co. KGaA, Henkelstrasse 67, D-40191 Düsseldorf, Germany;3. Henkel Adhesives, 10 Finderne Avenue, Bridgewater, NJ 08807, USA;1. Aero d.d., Ipavčeva ulica 32, 3000 Celje, Slovenia;2. Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva cesta 5, 1000 Ljubljana, Slovenia |
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| Abstract: | In this work, metal chelate zirconium acetylacetonate (ZrACA) was added into acrylic polymers with self-adhesive properties. These acrylic polymers, known as acrylic pressure-sensitive adhesives (PSA), were crosslinked with ZrACA to obtain acrylic self-adhesives with which to study the crosslinking reaction between carboxylic groups of the polymer chain and metal chelate crosslinking agent. |
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