Polarizability effect in silatranes and related compounds |
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| Institution: | 1. A.E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 664033 Irkutsk, Russia;2. G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603950 Nizhny Novgorod, Russia;1. Faculty of Arts and Science, Giresun University, Turkey;2. Dereli Vocational School, Giresun University, Turkey;3. Faculty of Arts and Sciences, Sinop University, Turkey;1. Department of Science and Environmental Studies, The Hong Kong Institute of Education, 10 Lo Ping Road, Tai Po, Hong Kong, China;2. Department of Biology and Chemistry, City University of Hong Kong, Tat Che Avenue, Kowloon, Hong Kong, China;1. Crystal Research Lab, Department of Physics, Anna University, Chennai 600 025, India;2. SAIF, Indian Institute of Technology Madras, Chennai 600 025, India;1. Berlin Joint EPR Lab, Freie Universität Berlin, Arnimallee 14, 14195 Berlin, Germany;2. Light Technology Institute, Karlsruhe Institute of Technology, Engesserstrasse 13, 76131 Karlsruhe, Germany;1. Namık Kemal University, Department of Chemistry, 59030 Tekirdag, Turkey;2. Cumhuriyet University, Department of Science Education, 58040 Sivas, Turkey;3. Namık Kemal University, Vocational School of Technical Science, 59030 Tekirdag, Turkey;1. School of Environmental & Municipal Engineering, North China University of Water Resources and Electric Power, ZhengZhou, He’nan 450011, People’s Republic of China;2. College of Chemistry & Chemical Engineering, YangZhou University, YangZhou, Jiangsu 225002, People’s Republic of China |
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| Abstract: | The dipole moments (μ) of the molecules, the dipole moments (μDA) and the length (dDA) of the Si ← N bonds, and the electrochemical oxidation potentials (Ep) of Si-substituted silatranes, the dipole moments (μhs) of the molecules of Si-substituted 3-homosilatranes as well as the enthalpies of formation (ΔH0) of the intermolecular complexes of SiF4 with aniline derivatives depend not only on the inductive and resonance effects, but also on the polarizability of substituents which can be characterized by the σα constants. |
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