Electrolytic partial fluorination of organic compounds 84: Anodic mono- and difluorination of benzylphosphonate derivatives |
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| Affiliation: | 1. CQC, Department of Chemistry, University of Coimbra, Rua Larga, 3004-535 Coimbra, Portugal;2. Departamento de Química & QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal;1. Department of Chemistry, Guru Nanak Dev University, Amritsar 143005, Punjab, India;2. Department of Chemistry, Durban University of Technology, Durban 4000, South Africa;3. Department of Medicine, University of California, San Francisco, CA, USA;1. Division of Applied Chemistry, Institute of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Nakamachi, Koganei 184-8588, Japan;2. Asahi Glass Co. Ltd., Research Center, Kanagawa Ku, Yokohama 221-8755, Japan;1. Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, 4 Takeda, Kofu, Yamanashi 400-8510, Japan;2. Clean Energy Research Center, University of Yamanashi, 4 Takeda, Kofu, Yamanashi 400-8510, Japan;3. Fuel Cell Nanomaterials Center, University of Yamanashi, 6-43 Miyamae, Kofu, Yamanashi 400-0021, Japan;1. Graduate School of Engineering, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan;2. Molecular Chirality Research Center, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan |
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| Abstract: | Anodic fluorination of benzylphosphonate derivatives was carried out under various electrolytic conditions to provide the corresponding α-mono- and/or α,α-difluoro-products in moderate to good yields. It was found that the selectivity of fluorinated products was depending on the molecular structures of the starting substrates and the electrolytic conditions. |
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