The rotational spectrum of bromoacetyl chloride |
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| Affiliation: | 1. Department of Chemistry, Sathyabama Institute of Science and Technology, Chennai 119, India;2. Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology, Vellore, India;3. Department of Chemical Engineering, Sathyabama Institute of Science and Technology, Chennai 119, India |
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| Abstract: | The rotational spectrum of bromoacetyl chloride, BrCH2COCl, has been assigned using a pulsed molecular beam Fourier transform microwave spectrometer. It has been possible to determine the rotational and quartic centrifugal distortion constants of the energetically favoured conformer (anti-periplanar) as well as the complete bromine and chlorine quadrupole coupling tensors including their off diagonal elements for the following isotopomers: 79BrCH2CO35Cl, 81BrCH2CO35Cl, 79BrCH2CO37Cl, and 81BrCH2CO37Cl. Experimental results are supported by quantum chemical calculations. |
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