| 7-氯-[1，2，3，4]-四氢吩嗪-[2，3]-并富勒烯[60]的合成 |
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| 引用本文： | 文丽君,曾和平,杨定乔.7-氯-[1，2，3，4]-四氢吩嗪-[2，3]-并富勒烯[60]的合成[J].化学研究与应用,2008,20(10). |
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| 作者姓名： | 文丽君 曾和平 杨定乔 |
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| 作者单位： | 1. 海南医学院药学系,海南,海口,571101
2. 华南师范大学,化学与环境学院,广东,广州,510631 |
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| 摘 要： | 60富勒烯及其衍生物因其结构的特殊性,在有机超导、分子磁性、有机发光材料、分子器件、非线性光学活性、能量代谢和生物活性等1]方面表现出独特的性能和潜在的应用前景,是非常活跃的研究领域之一.
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| 关 键 词： | 7-氯-[1 2 3 4]-四氢吩嗪-[2 3]-并富勒烯[60] 富勒烯衍生物 Diels-Alder环加成反应 合成 |
The synthesis of 7-chloro-[1,2,3,4]-tetrahydrophenazine-[2,3]- fullerene C60 |
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| WEN Li-jun,ZENG He-ping,YANG Ding-qiao.The synthesis of 7-chloro-[1,2,3,4]-tetrahydrophenazine-[2,3]- fullerene C60[J].Chemical Research and Application,2008,20(10). |
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| Authors: | WEN Li-jun ZENG He-ping YANG Ding-qiao |
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| Abstract: | 7-chloro-1,2,3,4]-tetrahydrophenazine-2,3]-fullerene C60 has been firstly prepared by the Diels-Alder reaction of C60 with 6-chloro-2,3-bis(bromomethyl)-quinoxaline,which is obtained by the condensation reaction of 1,4-dibromo-2,3-butanedione with 4-chloro-1,2-phenylene-diamine.The structure of the compound is identified by UV,IR,MS,1H NMR and 13C NMR. |
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| Keywords: | 7-chloro-[1 2 3 4]-tetrahydrophenazine-[2 3]-fullerene C60 fullerene(C60)derivatives Diels-Alder reactions synthesis |
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