| 一维链状有机锡配位聚合物[(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n的合成及晶体结构 |
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| 引用本文： | 尹汉东,王传华,王勇,马春林. 一维链状有机锡配位聚合物[(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n的合成及晶体结构[J]. 无机化学学报, 2001, 17(6): 896-900 |
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| 作者姓名： | 尹汉东 王传华 王勇 马春林 |
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| 作者单位： | 尹汉东（聊城师范学院化学系,聊城,252059）;王传华（聊城师范学院化学系,聊城,252059）;王勇（聊城师范学院化学系,聊城,252059）;马春林（聊城师范学院化学系,聊城,252059） |
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| 基金项目： | 教育部骨干基金和山东省自然资助项目(No.Y2000B08)科学基金 |
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| 摘 要： | [(PhCH2)3Sn·(O2CC5H4N)·(H2O)]n was synthesized by the reaction of 4-pyridine car-boxylic acid with the tribenzyltin oxide and was characterized by IR,1H NMR and MS.Its crystal structure was determined by X-ray single crystal diffraction.The crystal belongs to monoclinic.The space group P21/c with unit cell parameters a=1.2241(8)nm,b=0.9660(6)nm,c=2.3708(15)nm,β=102.722(12)°,V=2.734(3)nm3,Z =4,Dc=1.298g·cm-3.In crystal,the tin atom rendered five-coordinate in a trigo nal bipyramidal structure which is bridged by 4-pyridine carboxy-late into one-dimensional chain polymers.
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| 关 键 词： | 一维无限链 有机锡配合物 4-吡啶甲酸 合成晶体结构 |
| 收稿时间： | 2001-05-28 |
| 修稿时间： | 2001-05-28 |
Synthesis and Crystal Structure of the One-dimensional Infinite Chain OrganotinCoordination Polymer, [ (PhCH2)3Sn |
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| YIN Han-Dong,WANG Chuan-Hu,WANG Yong and MA Chun-Lin. Synthesis and Crystal Structure of the One-dimensional Infinite Chain OrganotinCoordination Polymer, [ (PhCH2)3Sn[J]. Chinese Journal of Inorganic Chemistry, 2001, 17(6): 896-900 |
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| Authors: | YIN Han-Dong WANG Chuan-Hu WANG Yong MA Chun-Lin |
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| Affiliation: | Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059,Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059,Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059 and Department of Chemistry, Liaocheng Teachers University, Liaocheng 252059 |
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| Abstract: | |
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| Keywords: | one-dimensional infinite organotin complex 4-pyridine carboxylic acid synthesis crystal structure |
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