Relevance of electron transfer mechanism in electrocatalysis: the reduction of organic halides at silver electrodes |
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| Authors: | Isse Abdirisak A Falciola Luigi Mussini Patrizia R Gennaro Armando |
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| Institution: | Department of Chemical Sciences, University of Padova, via Marzolo 1, 35131 Padova, Italy. |
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| Abstract: | The mechanism of dissociative electron transfer (ET) to a series of organic chlorides has been investigated both at an inert electrode and at a catalytic surface such as Ag; electrocatalysis is important only when breaking of the carbon-halogen bond is concerted with the ET. |
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