Kinetics and mechanism of oxidation of oxalate and malonate by diperiodatocuprate(III) |
| |
| Authors: | K. Bal Reddy |
| |
| Affiliation: | (1) Department of Chemistry, P.G. College of Science, Osmania University, 500 004 Hyderabad, India;(2) Institute of Inorganic Chemistry, University of Witten/Herdecke, Stockumer str. 10, 5810 Witten, FRG |
| |
| Abstract: | The kinetics of oxidation of oxalate and malonate by diperiodatocuprate(III) have been investigated. The orders with respect to [substrate] and [oxidant] are both unity. The rate of oxidation increased with increase in [OH–] and decrease in [KIO4]. The reactivity of malonate is higher than oxalate. A free radical mechanism is proposed based on the stoichiometry and products of oxidation. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
