Determination of radiation yields of ionogenic products of two-phase water-dibutylphosphate systems by capillary isotachophoresis |
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| Authors: | J Kuruc R Batista R Čech P Rajec |
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| Institution: | (1) Department of Nuclear Chemistry, Faculty of Natural Sciences, Comenius University, 84212 Bratislava, Slovak Republic;(2) Present address: IAEA Seibersdorf Laboratory, A-2444 Seibersdorf, Austria;(3) Present address: Blue Planet Ltd., Tren ianska 10, 821 09 Bratislava, Slovak Republic |
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| Abstract: | The main ionogenic radiolytical degradation products are monobutylphosphate, phosphoric acid, formic, acetic, propionic and butyric acids as the result of gamma-irradiation of two-phase water-dibutylphosphate system. The products were determined using capillary isotachophoresis. According two-phase theory the total (T
G(X)) and partial (GI(X) for aqueous phase and GII(X) for organic phase) radiation yields of products and decomposition of DBP in the radiolysis of two phase water-dibutylphosphate systems were calculated from the results.Dedicated to 65th birthday of prof. L. T. Bugaenko |
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