Coordination chemistry of perfluoroalkylated phosphorus(III) ligands |
| |
| Authors: | David Gudmunsen Danny R Paige Alison M Stuart |
| |
| Institution: | Department of Chemistry, University of Leicester, Leicester LE1 7RH, UK |
| |
| Abstract: | Palladium(II), platinum(II), rhodium(I), rhodium(III) and iridium(III) complexes of the tridecafluorohexyl-derivatised diphenylethylphosphinite (PPh2OC2H4Rf), phenyldiethylphosphonite {PPh(OC2H4Rf)2}, triethylphosphite {P(OC2H4Rf)3}, triphenylphosphinite (PPh2OC6H4-4-Rf), triphenylphosphonite {PPh(OC6H4-4-Rf)2}, ethyldiphenylphosphine (PPh2C2H4Rf), diethylphenylphosphine {PPh(C2H4Rf)2} and triethylphosphine {P(C2H4Rf)3} ligands are synthesized by conventional ligand displacement and/or halide-bridge cleaved reactions, and their spectroscopic parameters are compared with those for the related ligands lacking the tridecafluorohexyl ponytails. |
| |
| Keywords: | Fluorous Perfluoroalkylated Phosphine Phosphite Phosphonite Phosphinite Coordination chemistry Platinum group metals |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
