Enantioselective synthesis of homoallylic alcohols via a chiral In(III)-PYBOX complex |
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| Authors: | Lu Jun Hong Mei-Ling Ji Shun-Jun Loh Teck-Peng |
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| Affiliation: | Department of Chemistry, National University of Singapore, Singapore. |
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| Abstract: | In the presence of 20 mol% of a chiral catalytic complex prepared from In(OTf)(3) and chiral PYBOX, allyltributylstannane reacted with aldehydes to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (60-93% ee). |
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