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稳定剂KI对化学镀Ni-Fe-P-B合金性能的影响
引用本文:余祖孝,郝世雄,饶志由.稳定剂KI对化学镀Ni-Fe-P-B合金性能的影响[J].化学研究与应用,2010,22(1).
作者姓名:余祖孝  郝世雄  饶志由
作者单位:四川理工学院材料与化学工程系,材料腐蚀与防护四川省高校重点实验室,四川,自贡,643000
基金项目:材料腐蚀与防护四川省高校重点实验室科研基金 
摘    要:Influences of stabilizer (KI) on the corrosion performance of the Ni-Fe-P-B deposit alloys,were investigated using electrochemical methods,weightless corrosion and heat treatment.The results show that corrosion current density (0.1585mA·cm~(-2)),porosity(0.5 No.cm~(-2)) and weightless corrosion rate of the deposit (Ni-Fe-P-B) in corrosion media are lowest,when the stabilizer (KI) concentration is 8mg.L~(-1).Corrosion resistance of the deposit drops to a different degree in the range of 200℃~600℃,and slowly falls down when CKI=8mg.L~(-1).The lattice changes and diffusion layer forming of the deposit play important roles in the changes of corrosion performance in the different range of heat treatment.However,the hardness and abradability of testing alloy increase to a different degree in 200~400℃.When CKI=8mg.L~(-1),hardness of alloy is as high as 950HV after heat treatment at 400℃×1h,which is twice that of the as-plated coating.

关 键 词:化学镀Ni-Fe-P-B合金  稳定剂(KI)  耐腐蚀性能  显微硬度  热处理

Influences of stabilizer (KI) on properties of electroless plating Ni-Fe-P-B deposit alloys
YU Zu-xiao,HAO Shi-xiong,RAO Zhi-you.Influences of stabilizer (KI) on properties of electroless plating Ni-Fe-P-B deposit alloys[J].Chemical Research and Application,2010,22(1).
Authors:YU Zu-xiao  HAO Shi-xiong  RAO Zhi-you
Abstract:Influences of stabilizer (KI) on the corrosion performance of the Ni-Fe-P-B deposit alloys,were investigated using electrochemical methods,weightless corrosion and heat treatment.The results show that corrosion current density (0.1585mA·cm~(-2)),porosity(0.5 No.cm~(-2)) and weightless corrosion rate of the deposit (Ni-Fe-P-B) in corrosion media are lowest,when the stabilizer (KI) concentration is 8mg.L~(-1).Corrosion resistance of the deposit drops to a different degree in the range of 200℃~600℃,and slowly falls down when CKI=8mg.L~(-1).The lattice changes and diffusion layer forming of the deposit play important roles in the changes of corrosion performance in the different range of heat treatment.However,the hardness and abradability of testing alloy increase to a different degree in 200~400℃.When CKI=8mg.L~(-1),hardness of alloy is as high as 950HV after heat treatment at 400℃×1h,which is twice that of the as-plated coating.
Keywords:electroless coatings Ni-Fe-P-B alloy  stabilizer (KI)  corrosion resistance  microhardness  heat treatment
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