| 具有Gemini表面活性ATRP引发剂的合成 |
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| 引用本文： | 程传杰,刘二静,付全磊,申亮,郑义. 具有Gemini表面活性ATRP引发剂的合成[J]. 合成化学, 2012, 20(3): 340-341,362 |
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| 作者姓名： | 程传杰 刘二静 付全磊 申亮 郑义 |
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| 作者单位： | 江西科技师范大学化学化工学院,江西南昌,330013 |
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| 基金项目： | 国家自然科学基金资助项目，江西省自然科学基金资助项目 |
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| 摘 要： | 以2-溴异丁酰溴、N,N-二甲基乙醇胺、1,6-二溴己烷为主要原料,通过两步反应合成了一种新型具有Gemini表面活性的ATRP引发剂——N1,N6-双[2-(2-溴异丁酰氧基)乙基]-N1,N1,N6,N6-四甲基己烷-1,6-二溴化铵,总收率70%,其结构经1H NMR,IR和元素分析表征。
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| 关 键 词： | ATRP引发剂 Gemini表面活性剂 ATRP 合成 |
Synthesis of a Novel Gemini Surface-active ATRP Initiator |
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| CHENG Chuan-jie , LIU Er-jing , FU Quan-lei , SHEN Liang , ZHEN Yi. Synthesis of a Novel Gemini Surface-active ATRP Initiator[J]. Chinese Journal of Synthetic Chemistry, 2012, 20(3): 340-341,362 |
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| Authors: | CHENG Chuan-jie LIU Er-jing FU Quan-lei SHEN Liang ZHEN Yi |
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| Affiliation: | CHENG Chuan-jie,LIU Er-jing,FU Quan-lei,SHEN Liang,ZHEN Yi(School of Chemistry and Chemical Engineering, Jiangxi Science & Technology Normal University,Nanchang 330013,China) |
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| Abstract: | A novel Gemini surface-active ATRP initiator,N1,N6-di[2-(2-bromo-isobutyryloxy)ethyl]-N1,N1,N6,N6-tetramethyl-hexane-1,6-ammonium dibromide in total yield of 70%,was synthesized by a two-step reaction from 2-bromoisobutyryl bromide,N,N-dimethyl ethanolamine and 1,6-dibromohexane.The structure was characterized by 1H NMR,IR and elemental analysis. |
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| Keywords: | ATRP initiator Gemini surfactant ATRP synthesis |
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