| 联邻甲苯胺缩PMBP及其配合物的合成 |
| |
| 引用本文： | 颜莉,楚天杰,严智能,赵吉寿.联邻甲苯胺缩PMBP及其配合物的合成[J].合成化学,2012,20(3):386-388. |
| |
| 作者姓名： | 颜莉 楚天杰 严智能 赵吉寿 |
| |
| 作者单位： | 云南民族大学民族药资源化学国家民委-教育部重点实验室,云南昆明,650031 |
| |
| 基金项目： | 国家自然基金资助项目，国家民委教育部重点实验室资助项目 |
| |
| 摘 要： | 以联邻甲苯胺和1-苯基-3-甲基-4-苯甲酰基吡唑啉酮(PMBP)为原料,采用固相法合成了两种新型Schiff碱——联邻甲苯胺单缩PMBP(L’)和联邻甲苯胺双缩PMBP(L);L分别与Cu(Ⅱ),Ni(Ⅱ)和Co(Ⅱ)配合制得三个对应的Schiff碱配合物,其结构经UV,1H NMR,IR和元素分析表征。
|
| 关 键 词： | 吡唑啉酮 Schiff碱 配合物 合成 |
Synthesis of Tolidine-PMBP and Its Complexes |
| |
| YAN Li
,
CHU Tian-jie
,
YAN Zhi-neng
,
ZHAO Ji-shou.Synthesis of Tolidine-PMBP and Its Complexes[J].Chinese Journal of Synthetic Chemistry,2012,20(3):386-388. |
| |
| Authors: | YAN Li CHU Tian-jie YAN Zhi-neng ZHAO Ji-shou |
| |
| Institution: | (Key Laboratory of Ethnic Medicine Resource Chemistry,State Ethnic Affairs Commission and Ministry of Education,Yunnan University of Nationalities,Kunming 650031,China) |
| |
| Abstract: | Two novel Schiff bases,tolidine-PMBP(L′) and tolidine-bisPMBP(L),were synthesized from ortho-tolidine and 1-phenyl-3-methyl-4-benzoyl-pyrazolone(PMBP) by solid method.Three complexes of L with Co(Ⅱ),Cu(Ⅱ) or Ni(Ⅱ) were prepared.The structures were characterized by UV,1H NMR,IR and elemental analysis. |
| |
| Keywords: | pyrazolone Schiff base complex synthesis |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
