| 新型希夫碱型钳形人工受体的微波合成及其对中性分子的识别性能 |
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| 引用本文： | 张嫦,谭炯,赵志刚. 新型希夫碱型钳形人工受体的微波合成及其对中性分子的识别性能[J]. 合成化学, 2012, 20(4): 482-485,489 |
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| 作者姓名： | 张嫦 谭炯 赵志刚 |
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| 作者单位： | 西南民族大学化学与环境保护工程学院,四川成都,610041 |
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| 基金项目： | 国家外专局资助项目，中央高校基本科研业务费专项优秀团队及重大孵化项目 |
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| 摘 要： | 以对苯二甲酸为起始原料,设计并合成了8个新型的芳环钳形人工受体(3a～3h),其结构经1H NMR,IR,ESI-MS和元素分析表征。利用UV-Vis滴定法初步考察了3a～3h对中性分子(邻苯二胺,间苯二胺,对苯二胺和二苯甲酮)的识别性能,结果表明3a～3h对其具有良好的识别性能。
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| 关 键 词： | 人工受体 合成 微波辐射 分子识别性能 |
Microwave Assisted Synthesis of Novel Schiff Base Molecular Tweezer Artificial Receptors and Its Molecular Recognition Properties on Neutral Molecular |
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| ZHANG Chang , TAN Jiong , ZHAO Zhi-gang. Microwave Assisted Synthesis of Novel Schiff Base Molecular Tweezer Artificial Receptors and Its Molecular Recognition Properties on Neutral Molecular[J]. Chinese Journal of Synthetic Chemistry, 2012, 20(4): 482-485,489 |
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| Authors: | ZHANG Chang TAN Jiong ZHAO Zhi-gang |
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| Affiliation: | (College of Chemistry and Environmental Protection Engineering,Southwest University for Nationalities,Chengdu 610041,China) |
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| Abstract: | Eight new Schiff base molecular tweezer artificial receptors(3a~3h)were designed and synthesized from terephthalic acid.The structures were characterized by 1H NMR,IR,ESI-MS and elemental analysis.The recognition properties of 3a~3h on neutral molecules(o-benzenediamine,m-benzenediamine,p-benzenediamine and diphenyl-ketone) were investigated by UV titration.The results showed that 3a~3h exhibited good recognition on neutral molecules. |
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| Keywords: | artificial receptor synthesis microwave irradiation molecular recognition property |
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