|
|||||
|
|
| 聚双(6-咔唑基己氧基)磷腈的合成 | |
| 引用本文： | 屈玉峰,蒋晓东,曹林洪,方瑜,罗炫,张庆军,孙连来,黄进,刘红婕. 聚双(6-咔唑基己氧基)磷腈的合成[J]. 合成化学, 2012, 20(1): 98-100,103 |
| 作者姓名： | 屈玉峰 蒋晓东 曹林洪 方瑜 罗炫 张庆军 孙连来 黄进 刘红婕 |
| 作者单位： | 1. 中国工程物理研究院激光聚变研究中心,四川绵阳621900;西南科技大学四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地&极端条件物质特性实验室,四川绵阳621010 2. 中国工程物理研究院激光聚变研究中心,四川绵阳,621900 3. 西南科技大学四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地&极端条件物质特性实验室,四川绵阳,621010 |
| 摘 要： | 以PCl5和NH4Cl为原料采用"一步法"合成了线型聚二氯磷腈(4);4与6-咔唑基己醇发生亲核取代反应合成了聚双(6-咔唑基己氧基)磷腈(5),其结构经1H NMR,31P NMR,IR和GPC表征。热分析结果表明,5具有良好的热稳定性和较高的玻璃化温度。 |
| 关 键 词： | 线型聚二氯磷腈 咔唑 合成 热性能 |
Synthesis of Poly [ bis ( hexan N-carbazol) ] phosphazene |
|
| QU Yu-feng , JIANG Xiao-dong , CAO Lin-hong , FANG Yu , LUO Xuan , ZHANG Qing-jun , Sun Lian-lai , HUANG Jing , LIU Hong-jie. Synthesis of Poly [ bis ( hexan N-carbazol) ] phosphazene[J]. Chinese Journal of Synthetic Chemistry, 2012, 20(1): 98-100,103 | |
| Authors: | QU Yu-feng JIANG Xiao-dong CAO Lin-hong FANG Yu LUO Xuan ZHANG Qing-jun Sun Lian-lai HUANG Jing LIU Hong-jie |
| Affiliation: | 1(1.Research Center of Laser Fusion,China Academy of Engineering Physics,Mianyang 621900,China; 2.State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials & Laboratory for Extreme Conditions Matter Properties,Southwest University of Science and Technology,Mianyang 621010,China) |
| Abstract: | Poly[bis(hexan N-carbazol)]phosphazene(5) was synthesized by nucleophile substitution reaction of hexan N-carbazol with linear polydichlorophosphazene which was straightly prepared by "one step" method from PCl5 and NH4Cl.The structure was characterized by 1H NMR,31P NMR,IR and GPC.The thermal analysis test results showed that 5 exhibited good thermal stability and a higher Tg. |
| Keywords: | linear polydichlorophosphazene carbazole synthesis thermal property |
| 本文献已被 CNKI 万方数据 等数据库收录！ | |