| 新型环三磷腈大分子的合成与性能研究 |
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| 引用本文： | 李晓丽,李志国,张诗尧,李斌,乔凯.新型环三磷腈大分子的合成与性能研究[J].合成化学,2012,20(2):153-155,160. |
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| 作者姓名： | 李晓丽 李志国 张诗尧 李斌 乔凯 |
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| 作者单位： | 1. 东北林业大学高分子阻燃新材料的分子设计与制备黑龙江省高校重点实验室,黑龙江哈尔滨,150040
2. 东北林业大学材料科学与工程学院,黑龙江哈尔滨,150040 |
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| 基金项目： | 国家自然科学基金资助项目，中央高校基本科研业务费专项资金资助项目，高等学校博士学科点专项科研基金资助项目 |
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| 摘 要： | 以六对羧基苯氧基环三磷腈为原料,通过羧基活化与缩合反应合成了一种新型的环三磷腈生物大分子(1),其结构经1H NMR,13C NMR,IR和MS表征。用UV,分子荧光光谱仪和共聚焦激光显微镜研究了1的水解性能和荧光性能。结果表明,1既具有生物可降解性,又具有荧光特性。
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| 关 键 词： | 环三磷腈 合成 水解性能 荧光性能 |
Synthesis and Performance Study of a Novel Cyclotriphosphazene Macromolecules |
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| LI Xiao-li
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LI Zhi-guo
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ZHANG Shi-yao
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LI Bin
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Qiao Kai.Synthesis and Performance Study of a Novel Cyclotriphosphazene Macromolecules[J].Chinese Journal of Synthetic Chemistry,2012,20(2):153-155,160. |
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| Authors: | LI Xiao-li LI Zhi-guo ZHANG Shi-yao LI Bin Qiao Kai |
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| Institution: | 1b(a.Heilongjiang Key Laboratory of Molecular Design and Preparation of Flame Retarded Materials; b.College of Material Science and Engineering,1.Northeast Forestry University,Harbin 150040,China) |
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| Abstract: | A novel cyclotriphosphazene macromolecule(1) was synthesized from hexa-(p-carboxyl-phenoxy)cyclotriphosphazene by reactions of carboxyl group activated and condensation.The structure of 1 was characterized by 1H NMR,13C NMR,FT-IR and MS.The hydrolytic degradation and fluorescent properties of 1 were investigated by UV,molecular luminescence spectrometer and the confocal laser scanning microscopy.The results showed that 1 have both hydrolytic degradation and fluorescent property. |
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| Keywords: | cyclotriphosphazene synthesis hydrolytic degradation fluorescence property |
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