Spontaneous current and DC bias induced current in nickel–metal hydride secondary battery |
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Authors: | Akira Doi |
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Institution: | (1) Department of Materials, Nagoya Institute of Technology, Nagoya 466-8555, Japan |
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Abstract: | The responses to biasing a nickel–metal hydride secondary battery with a dc pulse train, as well as to spontaneous discharging, are studied. A comparison is made between the current during biasing, i
e, and the current during off-biasing, i
g. It is suggested that both currents arise from the motion of the same charge carriers in the electrolyte, possibly the OH− ions. The only difference is that the motive force for i
e is a bias voltage, while the motive force for i
g is an open-circuit voltage of the battery. It is suggested that battery action proceeds by a single electrochemical reaction. In the course of discharging, the current drops abruptly by the formation of a resistive layer, possibly by depletion of the OH− ions in the vicinity of the positive electrode. |
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Keywords: | Nickel– metal hydride battery Discharge Positive electrode |
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