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Effects of ceria addition and pre-calcination temperature on performance of cobalt catalysts for Fischer-Tropsch synthesis
Authors:Reza Gheitanchi  Abbas Ali Khodadadi  Majid Taghizadeh and and Yadollah Mortazavi
Institution:(1) Chemical Engineering Department, Faculty of Engineering, Mazandaran University, Babol 47144, Iran;(2) Catalysis and Reaction Engineering Research Laboratory, University of Tehran,, Tehran, Iran;(3) Chemical Engineering Department, Faculty of Engineering, Mazandaran University, Babol 47144, Iran;(4) Catalysis and Reaction Engineering Research Laboratory, University of Tehran,, Tehran, Iran
Abstract:Summary The effect of ceria addition on the performance of 10 wt.% Co catalysts supported on SiO2 and Al2O3 for Fischer-Tropsch synthesis has been investigated. The catalysts were prepared by impregnation method and characterized by X-ray diffraction technique. The catalytic tests (P = 1 atm, T = 488 K, H2/CO = 2, GHSV=1800 h-1) indicate that with addition of ceria, significant changes in CO conversion and hydrocarbon selectivities are observed. Also, the experiments show that the performance of 10 wt.% Co-CeO2/Al2O3 depends on the ceria concentration as well as on the pre-calcination temperature.
Keywords:Fischer-Tropsch synthesis  ceria promoter  cobalt catalyst
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