含三唑-有机羧酸混合配体的配位聚合物

配位聚合物由于具有丰富的拓扑结构,并在客体交换与分离、气体存储、手性拆分、选择性催化、分子识别、荧光和磁性等方面有潜在应用,已成为当前配位化学、材料化学和晶体工程学的热点研究领域之一。本文结合近年来本课题组的研究工作及国内外相关研究进展,概述了含三唑-有机羧酸混合配体的配位聚合物结构和性质,着重讨论了有机羧酸配体在构筑配合物结构中的作用,并对今后的研究和发展方向进行了展望。

Coordination Polymers Constructed from Triazole and Carboxylate Mixed Ligands

The research of coordination polymers remain an extremely active field of material chemistry,coordination chemistry and crystal engineering in recent years due to their various network topologies and their potential applications in many aspects such as guest exchange/separation,gas storage,chiral resolution,selective catalysis,molecular recognition,fluorescence and magnetism.This paper summarizes the recent advancement on the structure of coordination polymer containing triazolate-carboxylate mixed ligands,which focuses chiefly on the role of carboxylate ligand in the crystal structure.The future research and development of coordination polymer constructed from triazole and carboxylate are also prospcted.