Copper-catalyzed hydrostannation of activated alkynes |
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Authors: | Leung Lai To Leung Sze Kar Chiu Pauline |
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Institution: | Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, PR China. |
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Abstract: | reactions: see text] (Ph3P)CuH]6 effectively catalyzes the hydrostannation of activated alkynes with exclusive regioselectivity for alpha-stannation. Syn hydrostannation is observed exclusively for alkynoates. Anti or syn hydrostannation adducts are obtained as products for alkynone substrates. |
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