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Copper-catalyzed hydrostannation of activated alkynes
Authors:Leung Lai To  Leung Sze Kar  Chiu Pauline
Institution:Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, PR China.
Abstract:reactions: see text] (Ph3P)CuH]6 effectively catalyzes the hydrostannation of activated alkynes with exclusive regioselectivity for alpha-stannation. Syn hydrostannation is observed exclusively for alkynoates. Anti or syn hydrostannation adducts are obtained as products for alkynone substrates.
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