| ATOM TRANSFER RADICAL POLYMERIZATION OF 2,5-BIS[（4-HEXYLOXYPHENYL）OXYCARBONYL]STYRENE |
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| 引用本文： | YiYi 范星河 Yong-fengZhao Xiao-fangChen Xin-huaWan 周其凤.ATOM TRANSFER RADICAL POLYMERIZATION OF 2,5-BIS[（4-HEXYLOXYPHENYL）OXYCARBONYL]STYRENE[J].高分子科学,2005,0(3):249-253. |
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| 作者姓名： | YiYi 范星河 Yong-fengZhao Xiao-fangChen Xin-huaWan 周其凤 |
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| 作者单位： | DepartmentofPolymerScience＆Engineering,CollegeofChemistry＆MolecularEngineering,PekingUniversity,Beijing100871,China |
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| 摘 要： | A side-on liquid crystalline monomer, 2,5-bis(4-hexyloxyphenyl)oxycarbonyl]styrene) (HPCS), was successfully polymerized via atom transfer radical polymerization (ATRP). The polymerization was catalyzed by CuBr/PMDETA in chlorobenzene at 90℃ with (1-bromoethyl)benzene as the initiator. The polymers have narrow MWD. It is the second example of mesogen-jacketed liquid crystalline polymer (MJLCP) prepared by ATRP.
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| 关 键 词： | 原子转移射线聚合法 2 5-双[（4-已基羟苯基）羟基碳酰基]苯乙烯 液晶聚合体 聚合反应 光子 共聚物 |
| 收稿时间： | 2004-02-11 |
| 修稿时间： | 2004-03-12 |
ATOM TRANSFER RADICAL POLYMERIZATION OF 2,5-BIS[(4-HEXYLOXYPHENYL)OXYCARBONYL]STYRENE |
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| Yi Yi,Xing-he Fan,Yong-feng Zhao,Xiao-fang Chen,Xin-hua Wan,Qi-feng Zhou.ATOM TRANSFER RADICAL POLYMERIZATION OF 2,5-BIS[(4-HEXYLOXYPHENYL)OXYCARBONYL]STYRENE[J].Chinese Journal of Polymer Science,2005,0(3):249-253. |
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| Authors: | Yi Yi Xing-he Fan Yong-feng Zhao Xiao-fang Chen Xin-hua Wan Qi-feng Zhou |
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| Institution: | Department of Polymer Science & Engineering, College of Chemistry & Molecular Engineering, |
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| Abstract: | A side-on liquid crystalline monomer, 2,5-bis(4-hexyloxyphenyl)oxycarbonyl]styrene) (HPCS), was successfully polymerized via atom transfer radical polymerization (ATRP). The polymerization was catalyzed by CuBr/PMDETA in chlorobenzene at 90℃ with (1-bromoethyl)benzene as the initiator. The polymers have narrow MWD. It is the second example of mesogen-jacketed liquid crystalline polymer (MJLCP) prepared by ATRP. |
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| Keywords: | Atom transfer radical polymerization Liquid crystalline polymer RADICAL POLYMERIZATION TRANSFER ATOM example liquid crystalline polymer polymers narrow chlorobenzene initiator radical polymerization ATRP atom transfer styrene monomer |
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