Electrodeposition of Se on carbon-supported Pt nanoparticles by cyclic voltammetry |
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Authors: | Song Qian Li Hui Liu Junji Hu Shi |
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Institution: | 1.Department of Chemistry, School of Science, Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, Tianjin, 300072, China ;2.Institute of Energy, Hefei Comprehensive National Science Center, Hefei, 230026, China ; |
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Abstract: | Cyclic voltammetry (CV) is a powerful and popular electrochemical technique widely used to study the surface structure of materials through the electrochemical behaviors. Herein CV is utilized to study the electrochemical deposition of selenium (Se) on carbon black-supported Pt nanostructures. We synthesized carbon-loaded platinum nanoparticles (Pt/C) by microwave method and studied the electrochemical behavior of selenium on them. Through the experiment of changing the reverse potential, the corresponding relationship between the Se deposition peak and stripping peak was clarified and the deposition and stripping process of Se was proposed. Meanwhile, we synthesized cubic and octahedral nanocrystals of Pt, and used CV to study the Se deposition on these nanosctructures supported by carbon. It was found that the relative intensity of UPD peaks on Pt is different, as Ptcube@C is dominated by (100) and Ptoct@C electrode is dominated by (111) while Pt@C falls in between. |
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