Sonochemical synthesis of amide-functionalized metal-organic framework/graphene oxide nanocomposite for the adsorption of methylene blue from aqueous solution |
| |
Institution: | 1. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, 14115-4383 Tehran, Islamic Republic of Iran;2. Department of Chemistry, Iran University of Science and Technology, Tehran 16846-13114, Islamic Republic of Iran |
| |
Abstract: | Graphene oxide-Zn2(oba)2(bpfb)]·(DMF)5 metal-organic framework nanocomposite (GO-TMU-23; H2oba = 4,4′-oxybisbenzoic acid, bpfb = N,N′-bis-(4-pyridylformamide)-1,4-benzenediamine, DMF = N,N-dimethylformamide) is prepared through a simple and large-scale sonochemical preparation method at room temperature. The obtained nanocomposite is characterized by Field Emission Scanning Electron Microscopy (FE-SEM), powder X-ray diffraction (PXRD) and FT-IR spectroscopy. Additionally, the absorption ability of GO-TMU-23 nanocomposite toward cationic dye methylene blue was also performed. Significantly, GO-TMU-23 nanocomposite exhibits remarkably accelerated adsorption kinetics for methylene blue in comparison with the parent materials. The adsorption process shows that 90% of the dye has been removed and the equilibrium status has been reached in 2 min by using the nanocomposites as the adsorbent. |
| |
Keywords: | Metal-organic framework Sonochemistry Ultrasound Graphene oxide Nanocomposite Dye adsorption |
本文献已被 ScienceDirect 等数据库收录! |
|