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Ionene supported peroxodisulfates: Polymeric reagents for the oxidative deprotection of TMS and THP ethers and oxidative cleavage of the C=N bond in water
Authors:Moslem Mansour Lakouraj   Mahmood Tajbakhsh   Farhad Ramzanian-Lehmali  Keyvan Ghodrati
Affiliation:(1) Department of Chemistry, Faculty of Science, University of Kurdistan, 66177-15143 Sanandaj, Iran;(2) Faculty of Chemistry, Bu-Ali Sina University, 65178-38683 Hamadan, Iran
Abstract:Oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers, and deprotection of phenylhydrazones, semicarbazones, and oximes to their corresponding carbonyl compounds carried out in water at reflux condition using ionene supported peroxodisulfates is reported. The reagents are recyclable and products are obtained in excellent yield under environmentally benign conditions without overoxidation to carboxylic acid.
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