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Synthesis of S -Aryl/Alkyl Thiolcarbonates from Disulfides and Chloroformates in the Presence of the Zn/AlCl3 System
Authors:Barahman Movassagh and Maryam Tavoosi
Abstract:A simple, general, and high yielding method has been developed for the synthesis of S-aryl/alkyl-O-aryl/alkyl thiolcarbonates from various chloroformates and disulfides by reductive cleavage of the S–S bond with a Zn/AlCl3 system in dry acetonitrile at 80°C.
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