Kinetics of tritium isotope exchange between H2S and CH3OH vapor in glass vessels |
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Authors: | A. Wawer |
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Affiliation: | (1) Department of Chemistry, Warsaw University, Zwirki i Wigury 101, 02-089 Warszawa, Poland |
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Abstract: | Two different mechanisms of tritium exchange between and CH3OH vapor in glass vessels have been found: (i) bimolecular exchange in the gas phase, (ii) pseudomonomolecular exchange between gaseous and CH3OH adsorbed on the surface. The total and partial orders, rate constants and activation energies are given.
         ,                      CH3OH                ,                               : 1)                              2)                                        CH3OH,                          .                                  ,                              .
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